Thermal Cycling Aging Effect on the Reliability and Morphological Evolution of SnAgCu Solder Joints

Abstract

In solder ball grid array (BGA) technology, solder joint reliability is one of the critical issues in microelectronics manufacturing industries. In this reliability aging study, Sn3.5AgO.7Cu solder joints were subjected to accelerated temperature cycling (ATC) test in TBGA assembly. Fatigue fracture occurred, very close to the solder/intermetallic compound (IMC) interface, at the TBGA component side due to the larger coefficient of thermal expansion (CTE) mismatch compared to the PCB side. During reflow, needle-type and scallop-type morphologies of (Cu,Ni) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> IMCs were formed at the TBGA component and PCB interfaces. In the process of thermal cycling, a layer of (Ni,Cu) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</sub> IMC grew beneath the (Cu,Ni) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> IMC due to the out diffusion of Ni from the under bump metallization (UBM). After extended thermal cycling aging, Ni–Sn–P IMC was found between the (Ni,Cu) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</sub> IMC and the In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> P layer at the printed circuit board (PCB) interface. Grain ripening and spalling of (Cu,Ni) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> IMC grains into the solder joint was also observed in the process of thermal cycling. The spalling phenomena of (Cu,Ni) <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> IMCs was caused by interface structure change and cyclic shear stresses and strains incurred during temperature cycling.