Amplification of a cyclic mixed-metalloporphyrin tetramer from a dynamic combinatorial library through orthogonal metal coordinationElectronic supplementary information (ESI) available: Fig. S1–3: 1H NMR, 1H–1H COSY and 1H–1H NOESY spectra of (4,4′-bipy)⊂[(Zn-1)2/(Rh-2)2] at 300 K. See http://www.rsc.org/suppdata/cc/b1/b111019p/

Eugen Stulz, Yiu‐Fai Ng, Sonya M. Scott, Jeremy K. M. Sanders

Chemical Communications · 2002 · 58 citations · 11 references

Concepts

Abstract

A cyclic porphyrin tetramer, consisting of two bis-phosphine substituted zinc(II) porphyrin units and two Rh(III)TPP units, is selected and amplified virtually quantitatively from a dynamic combinatorial library using 4,4'-bipy as a scaffold and using orthogonal binding modes.

References

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