Concepedia

First example of samarium diiodide-promoted sequential cyclization and ring-expansion reactions of α-bromomethyl cyclic β-keto esters to homologated γ-keto esters

Eietsu Hasegawa, T. KITAZUME, Kimiko Z. Suzuki, Emi Tosaka

Tetrahedron Letters · 1998 · 45 citations · 13 references

DOI

Concepts

References

13

Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents

Philippe Girard, Jean‐Louis Namy, Henri B. Kagan · Journal of the American Chemical Society · 1980 · 1.3K citations

, , +12

Atom transfer cyclization reactions of .alpha.-iodo esters, ketones, and malonates: examples of selective 5-exo, 6-endo, 6-exo, and 7-endo ring closures

Dennis P. Curran, Chi Tai Chang · The Journal of Organic Chemistry · 1989 · 439 citations

, , +10

New Mechanistic Insights into Reductions of Halides and Radicals with Samarium(II) Iodide

Dennis P. Curran, Thomas L. Fevig, Craig P. Jasperse et al. · Synlett · 1992 · 281 citations

, , +15

A Mild and Convenient Method for the Reduction of Organic Halides by Using a SmI2-THF Solution in the Presence of Hexamethylphosphoric Triamide (HMPA)

Junji Inanaga, Mitsuhiro Ishikawa, Masaru Yamaguchi · Chemistry Letters · 1987 · 259 citations

, , +3

Rearrangement of suitably constituted aryl, alkyl, or vinyl radicals by acyl or cyano group migration

A. L. J. BECKWITH, Dennis M. O’Shea, Steven Westwood · Journal of the American Chemical Society · 1988 · 237 citations

, , +4