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A Mild and Convenient Method for the Reduction of Organic Halides by Using a SmI2-THF Solution in the Presence of Hexamethylphosphoric Triamide (HMPA)
258
Citations
4
References
1987
Year
Hexamethylphosphoric TriamideChemical EngineeringNovel OrganocatalystsEngineeringOrganic HalidesOrganic ChemistryOrganometallic CatalysisChemistryHalogenationSmi2-thf SolutionSynthetic ChemistryMild Reaction Conditions
Abstract A remarkable effect of HMPA was observed in the reduction of organic halides with a SmI2-THF solution. Various types of organic halides were reduced rapidly to the corresponding alkanes in almost quantitative yields under mild reaction conditions.
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