Concepedia

Deciphering the origin of cooperative catalysis by dirhodium acetate and chiral spiro phosphoric acid in an asymmetric amination reaction

Hemanta K. Kisan, Raghavan B. Sunoj

Chemical Communications · 2014 · 36 citations · 24 references

DOI

Concepts

Abstract

The mechanism of asymmetric amination of diazo-acetate by tert-butyl carbamate catalyzed by dirhodium tetra(trifluoro)acetate and chiral SPINOL-phosphoric acid is examined using DFT (M06 and B3LYP) computations. A cooperative participation of both catalysts is noticed in the stereo-controlling transition state of the reaction.

References

24

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David W. C. MacMillan · Nature · 2008 · 2.4K citations

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Diazo Compounds and <i>N</i>-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

Qing Xiao, Yan Zhang, Jianbo Wang · Accounts of Chemical Research · 2012 · 971 citations

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Transition-Metal-Catalyzed Carbonylation Reactions of Olefins and Alkynes: A Personal Account

Xiao‐Feng Wu, Xianjie Fang, Lipeng Wu et al. · Accounts of Chemical Research · 2014 · 571 citations

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Asymmetric Cooperative Catalysis of Strong Brønsted Acid–Promoted Reactions Using Chiral Ureas

Hao Xu, Stephan J. Zuend, Matthew G. Woll et al. · Science · 2010 · 495 citations · Full text

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Direct Catalytic Intermolecular α‐Allylic Alkylation of Aldehydes by Combination of Transition‐Metal and Organocatalysis

Ismail Ibrahem, Armando Córdova · Angewandte Chemie International Edition · 2006 · 402 citations · Full text

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