Synthesis of Chiral Bis-Thiazolines and Asymmetric Diels–Alder Reactions

Takehiko Nishio, Yasuhiro Kodama, Yuji Tsurumi

Phosphorus, sulfur, and silicon and the related elements · 2005 · 19 citations · 5 references

Concepts

Abstract

Abstract New chiral ligands, bis-thiazoline derivatives (sulfur analogues of known oxazolines) were prepared from chiral bis-(N-acylamino alcohols) with Lawesson's reagent. Bis-thiazolines thus obtained proved to be useful chiral ligands for metal in asymmetric Diels–Alder reaction.

References

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