Catalytic Cycle for the Asymmetric Hydrogenation of Prochiral Ketones to Chiral Alcohols: Direct Hydride and Proton Transfer from Chiral Catalysts <i>trans</i>-Ru(H)₂(diphosphine)(diamine) to Ketones and Direct Addition of Dihydrogen to the Resulting Hydridoamido Complexes

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTCatalytic Cycle for the Asymmetric Hydrogenation of Prochiral Ketones to Chiral Alcohols: Direct Hydride and Proton Transfer from Chiral Catalysts trans-Ru(H)2(diphosphine)(diamine) to Ketones and Direct Addition of Dihydrogen to the Resulting Hydridoamido ComplexesKamaluddin Abdur-Rashid, Michael Faatz, Alan J. Lough, and Robert H. MorrisView Author Information Department of Chemistry, University of Toronto 80 Saint George Street, Toronto Ontario M5S 3H6, Canada Cite this: J. Am. Chem. Soc. 2001, 123, 30, 7473–7474Publication Date (Web):July 7, 2001Publication History Received28 March 2001Revised13 June 2001Published online7 July 2001Published inissue 1 August 2001https://pubs.acs.org/doi/10.1021/ja015902uhttps://doi.org/10.1021/ja015902urapid-communicationACS PublicationsCopyright © 2001 American Chemical SocietyRequest reuse permissionsArticle Views3101Altmetric-Citations267LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (2)»Supporting Information Supporting Information SUBJECTS:Alcohols,Anions,Catalysts,Ketones,Precursors Get e-Alerts