Publication | Closed Access
The Catalyst Precursor, Catalyst, and Intermediate in the Ru<sup>II</sup>‐Promoted Asymmetric Hydrogen Transfer between Alcohols and Ketones
1K
Citations
19
References
1997
Year
X-ray CrystallographyChemical EngineeringEngineeringBiochemistryNatural SciencesCatalyst PrecursorNew InsightMolecular ComplexCatalysisAsymmetric Hydrogen TransferHydrogenChemistryCatalyst ActivationHomogeneous CatalysisMolecular CatalysisRuii-catalyzed Hydrogen TransferCatalytic Synthesis
New insight into the mechanism of catalysis. The purple 16-electron complex 1 and the yellow 18-electron complex 2 directly mediate the asymmetric, RuII-catalyzed hydrogen transfer between secondary alcohols and ketones. Both complexes were characterized by X-ray crystallography.
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