Physical Review · 1958 · 220 citations · 8 references
EngineeringMaterials SciencePhysicsElectronic MaterialsSemiconductor DevicesSemiconductor MaterialsDefects In Electronic MaterialsDevice CharacterizationRadiation Damage In MaterialsSemiconductor DefectsCarrier LifetimeCarrier Lifetime MeasurementFrenkel DefectsIrradiation DamageRadiation DamageRadiation Damage EffectsRadiation EffectsRadiation-induced Defects
The study measures minority carrier lifetime and related photovoltaic and particle voltaic effects in Si and Ge, analyzes radiation‑induced energy levels and capture cross sections, and compares displacement‑cross‑section curves to collision‑theory calculations. Minority carrier lifetime is 10⁴ times more sensitive to radiation defects than conductivity, enabling detection of as few as 10¹⁰ defects cm⁻³, and the study determined Frenkel‑defect thresholds of 14.5 ± 0.4 eV in Ge and 12.9 ± 0.6 eV in Si, though explanations for the tail in displacement‑cross‑section curves do not fully match calculations.
Minority carrier lifetime, $\ensuremath{\tau}$, in semiconductors is shown to be more sensitive, by a factor of ${10}^{4}$, to radiation-induced defects than the conductivity. Thus, in some cases, the introduction of as few as ${10}^{10}$ defects per ${\mathrm{cm}}^{3}$ can be detected by its effect on $\ensuremath{\tau}$. Both direct measurements of $\ensuremath{\tau}$, and measurements of dependent parameters (such as the photovoltaic effect and the particle voltaic effect) are described for Si and Ge. Using such parameters, and an electron accelerator, the minimum energy needed to produce a Frenkel defect was found to be 14.5\ifmmode\pm\else\textpm\fi{}0.4 ev in Ge and 12.9\ifmmode\pm\else\textpm\fi{}0.6 ev in Si. An analysis of the phenomenon shows how the location of the radiation-induced energy levels and the relative minority carrier capture cross sections can be determined experimentally. The shape of the curve of the displacement cross section versus the incident particle energy is compared to calculations from collision theory. Qualitative explanations for the observed "tail" on this curve are presented. Calculations based on these explanations fail to yield complete agreement with the experimental curves.
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Statistics of the Recombinations of Holes and Electrons
W. Shockley, W. T. Read · Physical Review · 1952 · 6.4K citations
Electron-Hole Recombination in Germanium
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