Concepedia

Development of a Donor−Acceptor Concept for Enzymatic Cross-Coupling Reactions of Aldehydes:  The First Asymmetric Cross-Benzoin Condensation

Pascal Dünkelmann, Doris Kolter‐Jung, Adam Nitsche, Ayhan S. Demir, Petra Siegert, Bettina Lingen, Martin J. Baumann, Martina Pohl, Michael Müller

Journal of the American Chemical Society · 2002 · 249 citations · 9 references

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Concepts

Abstract

Highly enantioenriched mixed benzoins are obtained selectively through a biocatalytical cross-coupling reaction of aromatic aldehydes using ThDP-dependent enzymes.

References

9

Magnesium amide bases and amido-Grignards. 1. Ortho magnesiation

Philip E. Eaton, Chih Hung Lee, Yusheng Xiong · Journal of the American Chemical Society · 1989 · 230 citations

, , +5

Enantioselective Synthesis of α-Hydroxy Ketones via Benzaldehyde Lyase-Catalyzed C−C Bond Formation Reaction

Ayhan S. Demir, Özge Şeşenoğlu, Elif Eren et al. · Advanced Synthesis & Catalysis · 2002 · 179 citations

, , +15

Benzoylformate Decarboxylase fromPseudomonas putida as Stable Catalyst for the Synthesis of Chiral 2-Hydroxy Ketones

Hans Iding, Thomas Dünnwald, Lasse Greiner et al. · Chemistry - A European Journal · 2000 · 166 citations · Full text

, , +17

Intermolecular pinacol cross coupling of electronically similar aldehydes. An efficient and stereoselective synthesis of 1,2-diols employing a practical vanadium(II) reagent

John H. Freudenberger, Andrei W. Konradi, Steven F. Pedersen · Journal of the American Chemical Society · 1989 · 138 citations

, , +10

Asymmetric benzoin reaction catalyzed by benzoylformate decarboxylase

Ayhan S. Demir, Thomas Dünnwald, Hans Iding et al. · Tetrahedron Asymmetry · 1999 · 101 citations · Full text

, , +11