Publication | Closed Access
A New η<sup>6</sup>-Anthraceno−Diphosphine−Silver(I) Complex and Molecular Light Switch Effect
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References
2000
Year
Inorganic ChemistryPhotochemistryNatural SciencesMechanistic PhotochemistryPhosphine MoleculeCh2cl2 SolutionMolecular BiologyMolecular SwitchChemistryLuminescence PropertyPhotophysical PropertyAg+ Ion
The emissive anthraceno−diphosphine 1 reacts with Ag+ ion to afford the nonemissive η6-anthraceno−Ag+ complex 2. Binding of a phosphine molecule to the latter in CH2Cl2 solution by a ligand substitution reaction triggers a strong photoluminescence.
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