Langmuir · 2010 · 61 citations · 18 references
Natural SciencesMaterials EngineeringMaterials ScienceAnalytical ChemistryPolymer ChemistrySensorsChemical SensorsGas SensorsHolographyOptical SensorsSensor MaterialsVolatile Organic CompoundsIndoor Volatile Organic CompoundsLaser AblationPolymer SensorsReal-time Voc SensorsSilicone Elastomer MaterialsVolatile Organic Compound DetectionVolatile Organic Compound MonitoringVolatile Organic Compound Sensing
There is a need to develop sensors for real-time monitoring of volatile organic compounds (VOCs) and hydrocarbon gases in both external and indoor environments, since these compounds are of growing concern in human health and welfare. Current measurement technology for VOCs requires sophisticated equipment and lacks the prospect for rapid real-time monitoring. Holographic sensors can give a direct reading of the analyte concentration as a color change. We report a technique for recording holographic sensors by laser ablation of silver particles formed in situ by diffusion. This technique allows a readily available hydrophobic silicone elastomer to be transformed into an effective sensor for hydrocarbon gases and other volatile compounds. The intermolecular interactions present between the polymer and molecules are used to predict the sensor performance. The hydrophobicity of this material allows the sensor to operate without interference from water and other atmospheric gases and thus makes the sensor suitable for biomedical, industrial, or environmental analysis.
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Coupled Wave Theory for Thick Hologram Gratings
H. Kogelnik · Bell System Technical Journal · 1969 · 4.8K citations
Eli Yablonovitch · Journal of the Optical Society of America B · 1993 · 1.5K citations
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Polymer Science and Technology
Chemistry International · 2010 · 823 citations · Full text
Natural Sciences, Materials Engineering, Materials Science +12