Reverse vesicles formed by hydrogen bonded arylamide-derived triammonium cyclophanes and hexaammonium capsule

Abstract

Hydrogen bonded rigid imine-based macrocycles and capsules have been reduced to cyclic triamines and two-layered hexaamines, the triammonium and hexaammonium derivatives of which are revealed to form reverse vesicles in organic liquids of low polarity, which are characterized by SEM, AFM, (HR)TEM, DLS and XRD.