Synthesis of (−)-terrecyclic acid A. Absolute configuration of terrecyclic acid A and quadrone

The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation

Robert E. Ireland, Richard H. Mueller, Alvin K. Willard · Journal of the American Chemical Society · 1976 · 807 citations

Natural Sciences, Chemistry, Organic Chemistry +7

Enolate Claisen rearrangement of esters from furanoid and pyranoid glycals

Robert E. Ireland, Suvit Thaisrivongs, Noel R. Vanier et al. · The Journal of Organic Chemistry · 1980 · 155 citations

Natural Sciences, Biochemistry, Chemistry +9

Mechanism and regioisomeric control in palladium(II)-mediated cycloalkenylations. A novel total synthesis of (.+-.)-quadrone

Andrew S. Kende, Bruce D. Roth, Pauline J. Sanfilippo et al. · Journal of the American Chemical Society · 1982 · 98 citations

Natural Sciences, Chemistry, Catalysis +7

Total synthesis of the Cephalotaxus alkaloids. Cephalotaxine, cephalotaxinone, and demethylcephalotaxinone

Steven M. Weinreb, Joseph Auerbach · Journal of the American Chemical Society · 1975 · 92 citations

Pharmacy, Medicinal Chemistry, Pharmacology +9

Total synthesis of dl-quadrone

Samuel J. Danishefsky, Kenward Vaughan, Robert C. Gadwood et al. · Journal of the American Chemical Society · 1981 · 79 citations

Natural Sciences, Chemistry, Analytical Chemistry +6