SmI2-induced reductive cross-coupling of carbonyl compounds with (α,β-unsaturated esters

Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents

Philippe Girard, Jean‐Louis Namy, Henri B. Kagan · Journal of the American Chemical Society · 1980 · 1.3K citations

Natural Sciences, Chemistry, Inorganic Chemistry +12

The Homoaldol Reaction, or How to Overcome Problems of Regio‐ and Stereo‐selectivity

Dieter Hoppe · Angewandte Chemie International Edition in English · 1984 · 238 citations

Natural Sciences, Chemistry, Catalysis +10

Conversion of ketones having δ, ϵ-π-functions to cyclopentanols by zinc-trimethylchlorosilane

E. J. Corey, Stephen G. Pyne · Tetrahedron Letters · 1983 · 211 citations

Natural Sciences, Chemical Engineering, Chemistry +6

Silicon in Synthesis. 10. The (Trimethylsilyl)allyl Anion: A .beta.-Acyl Anion Equivalent for the Conversion of Aldehydes and Ketones into .gamma.-Lactones

Ed Ehlinger, Phillip Magnus · Journal of the American Chemical Society · 1980 · 114 citations

Natural Sciences, Chemistry, Catalysis +7

Trichlorotitanium and alkoxytitanium homoenolates. Preparation, characterization, and utilization for organic synthesis

Eiichi Nakamura, Hiroji Oshino, Isao Kuwajima · Journal of the American Chemical Society · 1986 · 94 citations

Natural Sciences, Chemistry, Inorganic Chemistry +5