Concepedia

On the magnitudes and origins of the “anomeric effects”, “exo-anomeric effects”, “reverse anomeric effects”, and CX and CY bond -lengths in XCH2YH molecules

Saul Wolfe, Myung‐Hwan Whangbo, David J. Mitchell

Carbohydrate Research · 1979 · 169 citations · 48 references

Concepts

Natural SciencesChemistrySpectroscopyAnomeric ConfigurationCrystallographyMolecular BondingMolecular StructureMolecular SymmetrySteric EffectsAnomeric Configuration EffectsAnomeric EffectAnomeric Substituent EffectAnomerization MechanismsBond LengthsExo-anomeric EffectExoanomeric EffectSmall-molecule Crystallography

References

48

Interaction of orbitals through space and through bonds

Roald Hoffmann · Accounts of Chemical Research · 1971 · 1.5K citations

Natural Sciences, Chemistry, Orbital Mechanics +6

Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds

Saul Wolfe · Accounts of Chemical Research · 1972 · 785 citations

Natural Sciences, Chemistry, Inorganic Chemistry +7

The conformational properties of glycosidic linkages

R. U. Lemieux, Shinkiti Koto · Tetrahedron · 1974 · 269 citations

Life Sciences, Biochemistry, Carbohydrate Biochemistry +13

Solvation effects on conformational equilibria. Studies related to the conformational properties of 2-methoxytetrahydropyran and related methyl glycopyranosides

René Lemieux, André A. Pavia, J. C. Martin et al. · Canadian Journal of Chemistry · 1969 · 241 citations · Full text

Natural Sciences, Biochemistry, Chemistry +17

Stereoelectronic control in the cleavage of tetrahedral intermediates in the hydrolysis of esters and amides

Pierre Deslongchamps · Tetrahedron · 1975 · 233 citations

Natural Sciences, Biochemistry, Chemistry +13