Continuous-wave laser oscillation on the 1315nm transition of atomic iodine pumped by O2(a1Δ) produced in an electric discharge

Abstract

Laser action at 1315nm on the I(P1∕22)→I(P3∕22) transition of atomic iodine is conventionally obtained by a near-resonant energy transfer from O2(a1Δ) which is produced using wet-solution chemistry. The difficulties in chemically producing O2(a1Δ) has motivated investigations into purely gas phase methods to produce O2(a1Δ) using low-pressure electric discharges. In this letter, we report on the demonstration of a continuous-wave laser on the 1315nm transition of atomic iodine where the O2(a1Δ) used to pump the iodine was produced by a radio-frequency-excited electric discharge. The electric discharge was sustained in a He∕O2 gas mixture upstream of a supersonic cavity which is employed to lower the temperature of the continuous gas flow and shift the equilibrium of atomic iodine in favor of the I(P1∕22) state. The laser output power was 220mW in a stable cavity composed of two 99.99% reflective mirrors.