Direct synthesis of novel SiC@Al<sub>2</sub>O<sub>3</sub>core-shell epitaxial nanowires and field emission characteristics

Hao Cui, Li Gong, Yong Sun, G. Z. Yang, Chaolun Liang, Jun Chen, C. X. Wang

CrystEngComm · 2010 · 28 citations · 38 references

Concepts

Abstract

SiC@Al2O3 core-shell epitaxial nanowires have been synthesized via one-step process by simply heating evaporating Al source and C source on silicon substrate. Energy dispersive X-ray spectroscopy and transmission electron microscopy analysis of as-fabricated samples indicate that the core-shell nanowires consist of single-crystalline β-SiC core and thin cubic γ-Al2O3 shell. Epitaxial relationship is also observed between SiC core and Al2O3 shell. The corresponding growth model is proposed to describe the growth process of the core-shell epitaxial nanowires. Moreover, field emission measurement reveals the core-shell epitaxial nanowires have the excellent field emission property with low threshold electric field of 13.8 V μm−1.

References

38