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Models of Hierarchically Constrained Dynamics for Glassy Relaxation
1.5K
Citations
8
References
1984
Year
Relaxation ProcessEngineeringGlass-forming LiquidGlass MaterialComputational MechanicsSoft MatterReal SystemsGlass TransitionMechanicsThermodynamicsMaximum Time ScalePhysicsEntropyNatural SciencesCondensed Matter PhysicsApplied PhysicsGlassy MaterialsGlassy RelaxationCritical PhenomenonMultiscale Modeling
A class of models for relaxation in strongly interacting glassy materials is suggested. Degrees of freedom are divided into a sequence of levels such that those in level $n+1$ are locked except when some of those in level $n$ find the right combination to release them, this representing the hierarchy of constraints in real systems. The Kohlrausch anomalous relaxation law, $\mathrm{exp}[\ensuremath{-}{(\frac{t}{\ensuremath{\tau}})}^{\ensuremath{\beta}}]$, emerges naturally, and a maximum time scale is found which exhibits a Vogel-Fulcher-type temperature dependence.
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