Physical Review Letters · 1984 · 1.5K citations · 8 references
Natural SciencesMaterials SciencePhysicsComputational PhysicsDynamical SystemsThermodynamicsConstraint-based ModelingEquations Of StateMolecular DynamicsPhase TransitionsRelaxation MechanismsVariational FormulationConstrained DynamicsDynamics Of Constrained SystemsGlass RelaxationGlass TransitionGlassy Dynamics
A class of models for relaxation in strongly interacting glassy materials is suggested. Degrees of freedom are divided into a sequence of levels such that those in level $n+1$ are locked except when some of those in level $n$ find the right combination to release them, this representing the hierarchy of constraints in real systems. The Kohlrausch anomalous relaxation law, $\mathrm{exp}[\ensuremath{-}{(\frac{t}{\ensuremath{\tau}})}^{\ensuremath{\beta}}]$, emerges naturally, and a maximum time scale is found which exhibits a Vogel-Fulcher-type temperature dependence.
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The ‘universal’ dielectric response
A.K. Jonscher · Nature · 1977 · 5.5K citations
R. G. Palmer · Advances In Physics · 1982 · 601 citations