Concepedia

Controlling Mode Selectivity in Palladium-Catalyzed Bisdiene Carbocyclizations:  Optimizing for Cyclization-Trapping over Cycloisomerization

James M. Takacs, Scott D. Schroeder, Jianxin Han, Meg Gifford, Xun-tian Jiang, Twana Saleh, S. Vayalakkada, Amy H. Yap

Organic Letters · 2003 · 25 citations · 11 references

DOI

Concepts

Abstract

[reaction: see text] Screening combinations of five catalyst precursors with 13 phosphorus ligands identified cyclization catalysts that favor carbocyclization-trapping with N-hydroxyphthalimide over a competing cycloisomerization mode.

References

11

1,3-Aminoalcohols by reductive cleavage of isoxazolidines with molybdenum hexacarbonyl

Stefano Cicchi, Andrea Goti, Alberto Brandi et al. · Tetrahedron Letters · 1990 · 215 citations

, , +5

Palladium/Phosphite Catalyst Systems for Efficient Cross Coupling of Aryl Bromides and Chlorides with Phenylboronic Acid

Alexander Zapf, Matthias Beller · Chemistry - A European Journal · 2000 · 121 citations

, , +15

Intermediates in the palladium-catalyzed reactions of 1,3-dienes. The reaction of (.eta.1,.eta.3-octadiendiyl)palladium complexes with acidic substrates

P.W. Jolly, Richard Mynott, B. Raspel et al. · Organometallics · 1986 · 99 citations

, , +7

Palladium-Catalyzed Head-to-Head Telomerization of Isoprene with Amines

Susan M. Maddock, M. G. Finn · Organometallics · 2000 · 63 citations

, , +6

Homogeneous telomerization of 1,3-butadiene with alcohols in the presence of palladium catalysts modified by hybrid chelate ligands

Federica Benvenuti, Carlo Carlini, Mario Marchionna et al. · Journal of Molecular Catalysis A Chemical · 1999 · 41 citations

, , +16