Concepedia

Palladium-Catalyzed Head-to-Head Telomerization of Isoprene with Amines

Susan M. Maddock, M. G. Finn

Organometallics · 2000 · 63 citations · 13 references

DOI

Concepts

Abstract

The palladium complex of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP) catalyzes the telomerization of isoprene with several secondary amines with unprecedented levels of selectivity for the head-to-head isomer. A mechanism based on stereoelectronic control by a Pd−monophosphine adduct is proposed.

References

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