Palladium-Catalyzed Head-to-Head Telomerization of Isoprene with Amines - Concepedia

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Palladium-Catalyzed Head-to-Head Telomerization of Isoprene with Amines

60

Citations

13

References

2000

Year

Susan M. Maddock, M. G. Finn

Organometallics

Cross-coupling ReactionEngineeringPalladium-catalyzed Head-to-head TelomerizationHead-to-head IsomerOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryStereoelectronic ControlAsymmetric CatalysisPd−monophosphine AdductBiomolecular Engineering

Abstract

The palladium complex of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP) catalyzes the telomerization of isoprene with several secondary amines with unprecedented levels of selectivity for the head-to-head isomer. A mechanism based on stereoelectronic control by a Pd−monophosphine adduct is proposed.

References

	Year	Citations

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