Concepedia

Preparation and Some Properties of a Phosphorus(V) Complex of Tetra-<i>tert</i>-butylphthalocyanine

Kuninobu Kasuga, Lin Liang, Makoto Handa, Tamotsu Sugimori, Kimio Isa, Kenji Matsuura, Y. Takinami

Inorganic Chemistry · 1999 · 17 citations · 16 references

DOI

Concepts

Abstract

A phosphorus(V) complex of tetra-tert-butylphthalocyanine was prepared. The blue complex showed B and Q bands at 350 and 660 nm with a fluorescence peak at 680 nm in chloroform. In a CV, the complex showed three oxidative and three reductive waves. The following depicted here was tentatively proposed.

References

16

Metalloid porphyrins and phthalocyanines

Phillip Sayer, Martin Gouterman, Charles R. Connell · Accounts of Chemical Research · 1982 · 156 citations

, , +6

Higher oxidation level phthalocyanine complexes of chromium, iron, cobalt and zinc. Phthalocyanine radical species

Jerry Myers, Geoffrey W. Rayner Canham, A. B. P. Lever · Inorganic Chemistry · 1975 · 136 citations

, , +11

Preparation of group 15 (phosphorus, antimony, and bismuth) complexes of meso-tetra-p-tolylporphyrin (TTP) and x-ray crystal structure of [Sb(TTP)(OCH(CH3)2)2]Cl

Tanya Barbour, Warwick J. Belcher, Penelope J. Brothers et al. · Inorganic Chemistry · 1992 · 105 citations

, , +11

Synthesis of axial dialkoxy phosphorus(<scp>V</scp>)porphyrin derivatives—novel hypervalent phosphorus compounds

Hiroshi Segawa, Kazuhiko Kunimoto, Akio Nakamoto et al. · Journal of the Chemical Society Perkin Transactions 1 · 1992 · 89 citations

, , +6

New tetrapyrrolic macrocycle: .alpha.,.beta.,.gamma.-triazatetrabenzcorrole

Michiya Fujiki, Hisao Tabei, Kimio Isa · Journal of the American Chemical Society · 1986 · 78 citations

, , +6