Synthesis of axial dialkoxy phosphorus(<scp>V</scp>)porphyrin derivatives—novel hypervalent phosphorus compounds

Hiroshi Segawa, Kazuhiko Kunimoto, Akio Nakamoto, Takeo Shimidzu

Journal of the Chemical Society Perkin Transactions 1 · 1992 · 89 citations · 15 references

Concepts

Abstract

Water-stable, axial dialkoxy hypervalent phosphorus(V)tetraphenylporphyrins have been synthesised in a novel fashion by efficient substitution of axial chloride ligands of dichlorophosphorus(V)-tetraphenylporphyrin.

References

15