Concepedia

Asymmetric Epoxidation of Fluoroolefins by Chiral Dioxirane. Fluorine Effect on Enantioselectivity

O. Andrea Wong, Yian Shi

The Journal of Organic Chemistry · 2009 · 78 citations · 44 references

DOI

Concepts

Abstract

The asymmetric epoxidation of various fluoroolefins has been studied using chiral ketone catalyst, and up to 93% ee was achieved with fructose-derived ketone 1.

References

44

An Efficient Catalytic Asymmetric Epoxidation Method

Zhixian Wang, Yong Qiang Tu, Michael Frohn et al. · Journal of the American Chemical Society · 1997 · 618 citations

, , +9

Synthetic methods and reactions. 63. Pyridinium poly(hydrogen fluoride) (30% pyridine-70% hydrogen fluoride): a convenient reagent for organic fluorination reactions

George A. Olah, John T. Welch, Yashwant D. Vankar et al. · The Journal of Organic Chemistry · 1979 · 566 citations

, , +5

An Efficient Asymmetric Epoxidation Method for <i>trans</i>-Olefins Mediated by a Fructose-Derived Ketone

Yong Qiang Tu, Zhixian Wang, Yian Shi · Journal of the American Chemical Society · 1996 · 440 citations

, , +6

Organocatalytic Asymmetric Epoxidation of Olefins by Chiral Ketones

Yian Shi · Accounts of Chemical Research · 2004 · 439 citations

, , +10

Ketone-Catalyzed Asymmetric Epoxidation Reactions

Dan Yang · Accounts of Chemical Research · 2004 · 247 citations

, , +10