Influence of the laser pulse duration on laser-produced plasma properties

Abstract

In the framework of laser-induced plasma spectroscopy (LIPS) applications, time-resolved characteristics of laser-produced aluminium plasmas in air at atmospheric pressure are investigated for laser pulse durations ranging from 100 fs to 270 ps. Measurements show that for delays after the laser pulse longer than ∼100 ns, the plasma temperature increases slightly with the laser pulse duration, while the electron density is independent of it. In addition, as the pulse duration increases, the plasma radiation emission lasts longer and the spectral lines arise later from the continuum emission. The time dependence of the continuum emission appears to be similar whatever the duration of the laser pulse is, while the temporal evolution of the line emission seems to be affected mainly by the plasma temperature. Finally, as far as spectrochemical applications (such as LIPS) of laser-produced plasmas are concerned, this study highlights the importance of the choice of appropriate temporal gating parameters for each laser pulse duration.