GC‐MS characterization (Chemical lonization and electron impact modes) of the methyl esters and oxazoline derivatives of cyclopropenoid fatty acids

Abstract

The CI‐(CH 4 ) mass spectra of the methyl esters and the EI mass spectra of the oxazoline derivatives of three cyclopropenoid fatty acids (malvalic, sterculic and α ‐ hydroxy‐sterculic acid) from the seed oil of Pachira aquatica were found to be useful for structure elucidation of such compounds. Furthermore, some hitherto unknown minor fatty acids were identified and the nuclear magnetic resonance data of the oil and α‐hydroxysterculic acid methyl ester are presented.