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Determination of the MnF<sub>2</sub>and ZnF<sub>2</sub>crystal structure from the EPR and optical measurements of Mn<sup>2+</sup>
29
Citations
11
References
1985
Year
Crystal StructureMagnetic PropertiesEngineeringMagnetic ResonanceChemistryElectronic StructureOptical PropertiesElectron Paramagnetic ResonanceStructure DeterminationMaterials SciencePhysicsCrystal MaterialPhysical ChemistryQuantum ChemistryOptical MeasurementsCrystallographyCrystalline ParametersCrystal Structure DesignEpr Parameters DTransition Metal ChalcogenidesNatural SciencesApplied PhysicsCondensed Matter PhysicsMn2+ Ions
The authors calculate the crystalline parameters for MnF2 and ZnF2 from EPR and optical measurements on Mn2+ ions. The results support the structure data previously reported by Stout and Reed (1954) rather than that by Baur (1958). In addition, the fourth-order perturbation formulae for the EPR parameters D and E are derived.
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