Concepedia

Synthesis and Crystal Structure of a New 3D Scaffold-Like Compound [Mn(4,4′-bipy)(N3)2]n

Hao-Yu Shen, Dai‐Zheng Liao, Zong‐Hui Jiang, Shi‐Ping Yan, Bai-Wan Sun, Geng‐Lin Wang, Yao Xinkan, Honggen Wang

Chemistry Letters · 1998 · 30 citations · 8 references

DOI

Concepts

Abstract

Abstract A new 3D scaffold-like compound [Mn(4,4′-bipy)(N3)2]n has been synthesized and its structure determined by single-crystal X-ray analysis. The molecular structure consists of a three-dimensional network in which Mn2+ are linked by EE bridged azido ligands and 4,4′-bipy ligands. Magnetic measurement indicates that the overall magnetic behavior is weakly antiferromagnetic.

References

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