Concepedia

[N(CH<sub>3</sub>)<sub>4</sub>][Mn(N<sub>3</sub>)<sub>3</sub>]: A Compound with a Distorted Perovskite Structure through Azido Ligands

Franz A. Mautner, Roberto Cortés, Luís Lezama, Teófilo Rojo

Angewandte Chemie International Edition in English · 1996 · 184 citations · 15 references

DOI

Concepts

Abstract

Manganese(II) nitrate and tetramethylammonium azide react to give the title compound in which the azido groups function as end-to-end bridging lig-ands in all spatial directions, and whose structure can be described as corresponding to a distorted perovskite (section of the structure shown on the right). At higher temperatures the compound undergoes a reversible phase transition to a pseudo-cubic phase.

References

15

On the Curie points and high temperature susceptibilities of Heisenberg model ferromagnetics

G. S. Rushbrooke, P.J. Wood · Molecular Physics · 1958 · 664 citations

, , +16

Dinuclear copper(II) cryptates of macrocyclic ligands: synthesis, crystal structure, and magnetic properties. Mechanism of the exchange interaction through bridging azido ligands

Jacques Comarmond, Pierre Plumere, J.‐M. Lehn et al. · Journal of the American Chemical Society · 1982 · 302 citations

, , +16

Ferromagnetic nickel(II) polynuclear complexes with end-on azido as bridging ligand. The first nickel(II)-azido one-dimensional ferromagnetic systems

Joan Ribas, Montserrat Monfort, C. Díaz et al. · Inorganic Chemistry · 1994 · 155 citations

, , +14

Two new .mu.-azido nickel(II) uniform chains: syntheses, structures, and magneto-structural correlations

Albert Escuer, Ramón Vicente, Joan Ribas et al. · Inorganic Chemistry · 1993 · 142 citations

, , +11

The first ferromagnetic tetranuclear nickel(II) complex with a .mu.-azido bridge. Structure and magnetic properties of [Ni4(.mu.-N3)4(2-oxo-1,3-diaminopropane)2(2-hydroxo-1,3-diaminopropane)2](ClO4)2

Joan Ribas, Montserrat Monfort, R. Costa et al. · Inorganic Chemistry · 1993 · 135 citations

, , +15