Publication | Closed Access
Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO<sub>3</sub>)<sub>2</sub>(1,2‐bis(4‐pyridyl)ethane)<sub>1.5</sub>]<sub><i>n</i></sub>
800
Citations
25
References
1997
Year
Open-framework Ladder StructureSupramolecular AssemblyEngineeringSquare CavitiesChemistryPolymersBilayer MotifPolymer ChemistryMaterials ScienceInorganic ChemistryCoordination PolymersCovalent Bonded FrameworkSupramolecular ChemistrySupramolecular IsomerismSupramolecular PolymerBiomolecular EngineeringSelf-assemblyConformational FreedomCoordination Polymer
Bilayers or open-framework ladder structure? Which supramolecular isomer is formed from Co(NO3)2 and the nonrigid spacer 1,2-bis(2-pyridyl)ethane depends on the crystallization conditions. The open-framework coordination polymer contains large, square cavities of 10 × 10 Å. A section of the bilayer motif is shown on the right.
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