Journal of Vacuum Science and Technology · 1972 · 176 citations · 0 references
Natural SciencesMaterials SciencePhysicsPhysical ChemistrySpectroscopySurface ScienceElectronic SpectroscopyHydrogen AtomPhotoelectron SpectroscopySurface EnergeticsSurface PhysicsSurface SpectroscopyAdsorbate CharacterizationAdsorption EnergeticsExcitationField EmissionField Emission TunnelingHydrogen Atom SpectrumSurface Adsorption Spectroscopy
Total energy distributions of field emitted electrons from the tungsten (110) and (100) planes as a function of coverage by hydrogen and deuterium have been recorded utilizing a spherical deflection energy analyzer. The elastic tunneling resonance spectrum gives a plot of the “local density of states” in the adsorbate. The inelastic tunneling spectrum reveals those discrete excitation energies available in the adsorbate–substrate complex. These spectroscopic data have been used to infer the chemical nature of the binding states which have been observed in the flash desorption spectrum of hydrogen from tungsten.