Pigment & Resin Technology · 2007 · 149 citations · 26 references
Natural SciencesChemistryMaterials ScienceCorrosion ScienceFood ChemistryMetallurgyCorrosion ControlCorrosion InhibitorsCorrosion MechanismsCorrosion Of SteelsCorrosion TestingCorrosion-resistant MaterialsAdsorption InhibitionAdsorption IsothermsAdsorption KineticsCorrosion In Acidic MediaCorrosion Inhibition MechanismsCorrosion Inhibitor EffectsPhysical AdsorptionPlant Extract Inhibitors
Purpose To evaluate the effect of different parts of Carica papaya (leaves (LV), seeds (SD), heart wood (HW) and bark (BK)) as eco‐friendly and non‐toxic mild‐steel corrosion inhibitors in H 2 SO 4 at 30 to 60 o C. Design/methodology/approach Acid extracts of the different parts of Carica papaya were used as inhibitors in various corrosion tests. Gravimetric and gasometric techniques were used to characterise the mechanism of inhibition. Findings The LV, SD, HW and BK extracts were found to inhibit mild steel corrosion in H 2 SO 4 . The inhibition efficiencies of the plant's part extracts follow the trend: LV > SD > HW > BK. Inhibition efficiency increased with extracts concentration but decreased with temperature. Physical adsorption of the phytochemical components of the plant on the metal surface is proposed as the mechanism of inhibition. The experimental data fits well into the Langmuir and Temkin adsorption isotherms. Practical implications The plant extracts can be used in chemical cleaning and picking processes. Originality/value The research provides information on the possible use of the different parts of Carica papaya as sources of cheap eco‐friendly and non‐toxic corrosion inhibitors.
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