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Synthesis of Uridine 5′-(<scp>L</scp>-Arabinofuranosyl pyrophosphate) and the Structure of the UDP-<scp>L</scp>-arabinose Formed in Plants from UDP-α-<scp>D</scp>-xylopyranose
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1972
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BiosynthesisBioorganic ChemistryEngineeringBiochemistryBiotransformationNatural SciencesBiocatalysisL-arabinofuranosyl PyrophosphateGlycobiologyPlant Particulate FractionsPyranose Ring StructureNatural Product BiosynthesisPolysaccharideNatural Product SynthesisEnzymatic ModificationUridine 5′-Biomolecular Engineering
Uridine 5′-(L-arabinofuranosyl pyrophosphate) and uridine 5′-(β-L-arabinopyranosyl pyrophosphate) have been synthesized chemically and compared with the UDP-L-arabinose formed from UDP-α-D-xylopyranose and UDP-α-D-glucuronic acid by plant particulate fractions. It is concluded that the product of enzymic reaction has a pyranose ring structure.