Publication | Closed Access
Interaction of [Ru(dmp)<sub>2</sub>(dppz)]<sup>2+</sup> and [Ru(dmb)<sub>2</sub>(dppz)]<sup>2+</sup> with DNA: Effects of the Ancillary Ligands on the DNA-Binding Behaviors
260
Citations
42
References
2001
Year
Ancillary LigandMolecular BiologyMethyl GroupsNucleic Acid ChemistryDna ComputingMolecular RecognitionAncillary LigandsBiochemistryOligonucleotideDna ReplicationBiochemical InteractionBiomolecular InteractionStructural BiologyChromatinNatural SciencesNucleic Acid BiochemistryComplexes 1Molecular ComplexMolecular BiophysicsDna-binding BehaviorsMedicine
By the incorporation of methyl groups on the ancillary ligand of phen and bpy, different DNA-binding behaviors of complexes 1 and 2 were characterized. Different binding rates of the isomers of 2 with CT-DNA via CD spectra were observed through dialysis experiments but not with complex 1.
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