Surface crystallography and electronic structure of potassium yttrium tungstate

Abstract

Structural and electronic characteristics of KY(WO4)2 (KYW) (010) crystal surfaces have been studied using reflection high-energy electron diffraction (RHEED) and x-ray photoelectron spectroscopy (XPS). The results indicate that the crystal structure and chemical composition of the mechanically polished pristine surface is stoichiometrically well maintained as expected for KYW crystals. Combined measurements of RHEED and XPS as a function of 1.5 keV Ar+ ion irradiation of the KYW (010) surfaces indicate amorphization, partial loss of potassium atoms, and partial transformation of chemical valence state of tungsten from W6+ to a lower valence state, W0 state predominantly, which induces electronic states at the top of valence band.