Valence Band is the highest range of electron energy levels in a solid that is filled with electrons at absolute zero temperature, distinguishing it from higher-energy unoccupied states by representing the energetic limit of bound electronic states in insulators and semiconductors.
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Optical Properties and Electronic Structure of Amorphous Germanium
J. Tauc, R. Grigorovici, A. Vancu · physica status solidi (b) · 1966 · 10.7K citations
Resonating valence bonds: A new kind of insulator?
P. W. Anderson · Materials Research Bulletin · 1973 · 2.8K citations
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