Concepedia

Application of the Saegusa Oxidation to Trimethylsilyl Ethers of Diosphenols

Moonsun Kim, Laura A. Applegate, Oee‐Sook Park, Sundar Vasudevan, David S. Watt

Synthetic Communications · 1990 · 16 citations · 8 references

DOI

Concepts

Abstract

Abstract The Saegusa oxidation of trimethylsilyl ethers of diosphenols provided enediones and served as a key reaction in the conversion of δ2-picrasin B to 1β-hydroxy-12-methoxy-picrasa-3,12-diene-2,11-dione, a model for the A ring functionality of many guassinoids.

References

8

Synthesis of .alpha.,.beta.-unsaturated carbonyl compounds by palladium(II)-catalyzed dehydrosilylation of silyl enol ethers

Yoshihiko Ito, Toshikazu Hirao, Takeo Saegusa · The Journal of Organic Chemistry · 1978 · 861 citations

, , +5

New synthetic reactions of allyl alkyl carbonates, allyl .beta.-keto carboxylates, and allyl vinylic carbonates catalyzed by palladium complexes

Jiro Tsuji, Ichiro Minami · Accounts of Chemical Research · 1987 · 379 citations

, , +8

Oxidation of sterically hindered alcohols to carbonyls with dimethyl sulfoxide-trifluoracetic anhydride

Suchin Huang, Kanji Omura, Daniel Swern · The Journal of Organic Chemistry · 1976 · 158 citations

, , +6

The Reaction of Lithium Aluminum Hybride with Alcohols. Lithium Tri-t-butoxyaluminohydride as a New Selective Reducing Agent<sup>1,2</sup>

Herbert C. Brown, Richard F. McFarlin · Journal of the American Chemical Society · 1958 · 108 citations

, , +4

Advances in the chemistry of 2,3-epoxyalcohols. New methodology for contra-trans-diaxial opening and selective enediol oxidation

Brian A. McKittrick, Bruce Ganem · The Journal of Organic Chemistry · 1985 · 56 citations

, , +4