Concepedia

Heteroleptic Dipyrrin/Bipyridine Complexes of Ruthenium(II)

S.J. Smalley, Mark R. Waterland, Shane G. Telfer

Inorganic Chemistry · 2008 · 77 citations · 14 references

DOI

Concepts

Abstract

The synthesis and characterization of a series of heteroleptic dipyrrinato/2,2'-bipyridine complexes of ruthenium(II) are reported. Spectroscopic analysis, including resonance Raman, indicates that the complexes are only weakly emissive and that the dipyrrin and Ru --> bipyridine (metal-to-ligand charge transfer) chromophores are uncoupled.

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