Energy & Environmental Science · 2011 · 40 citations · 15 references
EngineeringMaterials EngineeringMaterials ScienceSemiconductor DevicesSemiconductor MaterialsThin FilmsPhotovoltaic DevicesPhotovoltaic MaterialsSemiconductor Thin FilmsSolar Cell MaterialsSolar CellsThin-film MaterialsConcentrationConcentrator PhotovoltaicsEnergy Conversion EfficiencyOhmic LossesPolycrystalline Thin FilmsSolar Cell CharacterizationSolar Cell FabricationThermal Effects
Using solar cells under concentrated illumination is known to improve the conversion efficiency while diminishing the active area, and thus material consumption. Recent concentrator cell designs tend to go to smaller devices, in the 0.5–1mm lateral range, enabling a better thermal evacuation due to higher surface to volume ratio. If the cell size is further reduced to the micrometric range, spreading resistance losses can be made vanishingly small. This is particularly interesting for thin film technology which has been limited up to now to very low concentrations, 1–10 suns, due to excessive resistive losses of the window layer and difficult thermal management of the cells, grown on glass substrates. In order to prove that high injection regime can be implemented on polycrystalline thin film solar cells, we fabricated Cu(In, Ga)Se2 (CIGS) thin film microcells with diameter from 7 μm to 150 μm, and characterized them under concentrated illumination. A 4% absolute efficiency increase is obtained at 120 suns, and current densities as high as 100 A cm−2 can be measured, without affecting the cell performances. The temperature increase under high fluxes is drastically reduced in microcells: less than 20 K at 1000 suns for microcells under 50 μm in diameter. These results show that the use of polycrystalline thin films under high concentration is indeed possible, with important technological consequences.
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Photovoltaic Technology: The Case for Thin-Film Solar Cells
A. Shah, P. Torres, R. Tscharner et al. · Science · 1999 · 1.3K citations · Full text
The chemical potential of radiation
P. Würfel · Journal of Physics C Solid State Physics · 1982 · 977 citations