Transition Between Band and Hopping Transport in Polymer Field‐Effect Transistors

Yu Yamashita, Junto Tsurumi, Felix Hinkel, Yugo Okada, Junshi Soeda, Wojciech Zajączkowski, Martin Baumgarten, Wojciech Pisula, Hiroyuki Matsui, Kläus Müllen,

Advanced Materials · 2014 · 70 citations · 30 references

Concepts

Abstract

Hall effect and slightly negative temperature dependence of the mobility in polymeric transistors are demonstrated. The semiconductor channel is based on a polycyclopentadithiophene-benzothiadiazole (CDT-BTZ) donor-acceptor copolymer film whose chain direction is oriented by mechanical compression at the surface of an ionic liquid. The mobility is 5.6 cm(2) V(-1) s(-1) at room temperature, and is further improved to 6.7 cm(2) V(-1) s(-1) at 260 K.

References

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