Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control · 2006 · 21 citations · 16 references
Natural SciencesMaterials EngineeringMaterials ScienceCorrosion ScienceMetallurgySurface ScienceCorrosion EngineeringCorrosion InhibitorsCorrosion KineticsCorrosion MechanismsCorrosion ThermodynamicsAdsorption PhenomenaCorrosion Inhibitor EffectsInhibitor AdsorptionLangmuir Adsorption ModelPotentiodynamic PolarizationProcess Inhibition
The inhibitive effect of thiosemicarbazide on the corrosion of cold rolled carbon steel in acidic media has been studied. For this investigation, a standard potentiodynamic polarisation technique was used to determine the corrosion rate and the inhibition efficiency and also to find out which adsorption isotherm governs the inhibition process. For this purpose, thiosemicarbazide was added to 0·5M H2SO4 in four concentrations ranging between 1 × 10−4M and 1 × 10−2M. Analysis of the experimental data shows that concentration has a strong influence on the efficiency of inhibition. Thermodynamics studies confirm that the inhibitor adsorption follows the Langmuir adsorption isotherm.
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Theory of Organic Corrosion Inhibitors
Francis M. Donahue, Ken Nobe · Journal of The Electrochemical Society · 1965 · 434 citations
1991 Whitney Award Lecture: Inhibitors—An Old Remedy for a New Challenge
G. Trabanelli · CORROSION · 1991 · 345 citations