Concepedia

Catalytic asymmetric [3,3]-rearrangements of allylic acetimidates

Johannes M. Bauer, René Peters

Catalysis Science & Technology · 2015 · 10 citations · 59 references

DOIFull text

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Concepts

Abstract

The rearrangement of non-halogenated acetimidates in combination with an enzymatic amide hydrolysis is attractive to get almost enantiopure allylic amines.

References

59

Mercury(<scp>II</scp>)‐ and Palladium(<scp>II</scp>)‐Catalyzed [3,3]‐Sigmatropic Rearrangements [New Synthetic Methods (46)]

Larry E. Overman · Angewandte Chemie International Edition in English · 1984 · 317 citations

, , +9

One-pot synthesis of trifluoroacetimidoyl halides

Kenji Tamura, Hiromichi Mizukami, Kazuhiro Maeda et al. · The Journal of Organic Chemistry · 1993 · 278 citations

, , +5

Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity

Carolyn E. Anderson, Larry E. Overman · Journal of the American Chemical Society · 2003 · 242 citations

, , +9

Thermal and mercuric ion catalyzed [3,3]-sigmatropic rearrangement of allylic trichloroacetimidates. 1,3 Transposition of alcohol and amine functions

Larry E. Overman · Journal of the American Chemical Society · 1974 · 202 citations

, , +8

Catalytic Asymmetric Rearrangement of Allylic <i>N</i>-Aryl Trifluoroacetimidates. A Useful Method for Transforming Prochiral Allylic Alcohols to Chiral Allylic Amines

Larry E. Overman, Carolyn E. Owen, Mary M. Pavan et al. · Organic Letters · 2003 · 170 citations

, , +6