Japanese Journal of Applied Physics · 1998 · 223 citations · 8 references
Natural SciencesMaterials EngineeringMaterials SciencePlasma PhysicsSemiconductor MaterialsThin FilmsChemical Vapor DepositionHigh-frequency Semiconductor DevicesHigh-temperature PlasmasSemiconductor Device MaterialsSilicon MaterialsThin-film DepositionCrystallinityCrystallinity AnalysisCrystallinity ChangesDefect DensityDeposition RatePlasma-enhanced Chemical Vapor DepositionPlasma-enhanced DepositionSilicon
The deposition of hydrogenated microcrystalline silicon (µc-Si:H) at a relatively high working pressure is performed using a conventional radio-frequency plasma-enhanced chemical vapor deposition method. Correlation of the deposition rate and crystallinity with deposition parameters, such as working pressure, flow rate, dilution ratio and input RF power, are studied. It was found that the deposition rate exhibits a maximum at around 4 Torr and that the crystallinity of films decreases monotonically with increasing pressure. The combination of SiH 4 depletion and high working pressure in the plasma is necessary to improve the crystallinity of films deposited at a high rate. Consequently, a high deposition rate of 9.3 Å/s is achieved with high crystallinity and low defect density.
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On the Way Towards High Efficiency Thin Film Silicon Solar Cells by the “Micromorph” Concept
J. Meier, P. Torres, R. Platz et al. · MRS Proceedings · 1996 · 248 citations · Full text