Applied Physics Letters · 2012 · 56 citations · 22 references
Natural SciencesElectrical EngineeringMaterials ScienceElectronic MaterialsPolymer EngineeringThin FilmsConducting PolymersConductive PolymersDielectricsElectrical ConductivityPolymer Thin FilmsThin Film Electrical PropertiesCharge Carrier DynamicsCharge TrapsConductionConductive Polymer Thin FilmsConductivity In Thin FilmsPolyimidesSpace-charge-limited CurrentTemperature Dependence
Space-charge-limited currents have been identified in thin polyimide film capacitor structures as the main conduction process in the very high temperature range from 320 °C to 400 °C before the breakdown. The transition field between the trap-filled-limit conduction and the trap-free conduction is reported versus temperature. Assuming an exponential distribution of the traps in the forbidden gap, both the characteristic temperature and trap energy are obtained at 446 °C and 62 meV, respectively. The total trap density is accurately estimated at 1.5 × 1017 cm−3 using the Kumar approximation [Kumar et al., J. Appl. Phys. 94, 1283 (2003)]. Finally, the mobility temperature dependence of free charges is reported between 1.6 × 10−6 and 2.3 × 10−6 cm2 V−1 s−1 in the range from 340 °C to 400 °C.
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Space-Charge-Limited Currents in Organic Crystals
Peter Mark, W. Helfrich · Journal of Applied Physics · 1962 · 994 citations