Concepedia

Chirality transfer based on reversible C–C bond formation/breaking in nickel(<scp>ii</scp>) complexes

Tatsuya Kawamoto, Narumi Suzuki, Takeshi Ono, Dafei Gong, Takumi Konno

Chemical Communications · 2012 · 11 citations · 18 references

DOI

Concepts

Abstract

The reaction of (1R)-(-)-myrtenal-derived benzothiazoline with nickel(II) acetate in ethanol exclusively gave a Schiff base-type nickel(II) complex having M helical configurational myrtenyl arms, which is reversibly converted to a non-innocent-type complex having additional S,S configurational asymmetric carbon centres.

References

18

Experimental Evidence for the Noninnocence of <i>o</i>-Aminothiophenolates:  Coordination Chemistry of <i>o</i>-Iminothionebenzosemiquinonate(1-) π-Radicals with Ni(II), Pd(II), Pt(II)

Diran Herebıan, E. Bothe, Eckhard Bill et al. · Journal of the American Chemical Society · 2001 · 177 citations

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Effective Chirogenesis in a Bis(metallosalphen) Complex through Host–Guest Binding with Carboxylic Acids

Sander J. Wezenberg, Giovanni Salassa, Eduardo C. Escudero‐Adán et al. · Angewandte Chemie International Edition · 2010 · 119 citations

, , +8

“Cofactor”-Controlled Enantioselective Catalysis

Paweł Dydio, Christophe Rubay, Tendai Gadzikwa et al. · Journal of the American Chemical Society · 2011 · 115 citations

, , +17

Coordination Chemistry of Tetradentate N-Donor Ligands Containing Two Pyrazolyl−Pyridine Units Separated by a 1,8-Naphthyl Spacer:  Dodecanuclear and Tetranuclear Coordination Cages and Cyclic Helicates

Stephen P. Argent, Harry Adams, T. Riis‐Johannessen et al. · Inorganic Chemistry · 2006 · 113 citations · Full text

, , +10

Chirality Transfer through Helical Motifs in Coordination Compounds

Cheng He, Yonggang Zhao, Dong Guo et al. · European Journal of Inorganic Chemistry · 2007 · 101 citations

, , +17