The Journal of Physical Chemistry Letters · 2010 · 43 citations · 47 references
EngineeringFree Protein MoleculesProtein Phase SeparationChemistryMolecular DynamicsProtein NanoparticlesSingle Molecule BiophysicsMolecular KineticsCarbon NanotubesBiophysicsNanotechnologyNanotubes StudiedSolution Nmr SpectroscopyNano ApplicationNmr Self-diffusionBiomolecular EngineeringSelf-diffusion Nmr SpectroscopyNanomaterialsProtein Dispersant BindingMedicine
Carbon nanotubes can be dispersed by a variety of molecules. We investigate the dynamics of protein-assisted carbon nanotube dispersion in water. We find that in equilibrium, only a small fraction of the dispersants is indeed adsorbed to the nanotube surface, while there is a fast exchange process between the adsorbed and free protein molecules. Self-diffusion NMR spectroscopy in combination with cryo-transmission electron microscopy imaging are employed.
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