Coupling of a 17-electron vinyl complex with chiral recognition: synthesis of the pure diastereoisomers of the bridging bis(carbene) complex [{Fe(C<sub>5</sub>Me<sub>5</sub>)(CO)(PMe<sub>3</sub>)}<sub>2</sub>{µ–C(OMe)[CH<sub>2</sub>]<sub>2</sub>–C(OMe)}][PF<sub>6</sub>]<sub>2</sub> - Concepedia

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Coupling of a 17-electron vinyl complex with chiral recognition: synthesis of the pure diastereoisomers of the bridging bis(carbene) complex [{Fe(C<sub>5</sub>Me<sub>5</sub>)(CO)(PMe<sub>3</sub>)}<sub>2</sub>{µ–C(OMe)[CH<sub>2</sub>]<sub>2</sub>–C(OMe)}][PF<sub>6</sub>]<sub>2</sub>

13

Citations

9

References

1993

Year

Stéphane Cron, Virginie Morvan, Claude Lapinte

Journal of the Chemical Society Chemical Communications

Abstract

The C–C bond-forming reaction by direct coupling of two chiral 17-electron metal vinyl units [Fe(C5Me5)(CO)(PMe3){C(OMe)CH2}]˙+ affords the µ-bis(carbene) dimetallic complex [{Fe(CBMe5)(CO)(PMe3)}2{µ-C(OMe)[CH2]2–C(OMe)}][PF6]25 with chiral recognition (major : minor = 2 : 1); the two diastereoisomers are isolated in a pure form.

References

	Year	Citations

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