John E. Bercaw

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

Gregory R. Fulmer, Alexander J. M. Miller, Nathaniel H. Sherden et al. · Organometallics · 2010 · 3.9K citations

Natural Sciences, Chemistry, Analytical Chemistry +9

.sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds

Mark E. Thompson, Steven M. Baxter, A. Ray Bulls et al. · Journal of the American Chemical Society · 1987 · 800 citations

Natural Sciences, Chemistry, Bioorganic Chemistry +12

Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalyst

Pamela J. Shapiro, Emilio E. Bunel, William P. Schaefer et al. · Organometallics · 1990 · 537 citations

Natural Sciences, Chemistry, Catalysis +9

Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solution

Pamela J. Shapiro, William P. Schaefer, Jay A. Labinger et al. · Journal of the American Chemical Society · 1994 · 472 citations

Natural Sciences, Chemical Engineering, Chemistry +16

Titanocene as an intermediate in reactions involving molecular hydrogen and nitrogen

John E. Bercaw, Robert H. Marvich, Larry G. Bell et al. · Journal of the American Chemical Society · 1972 · 341 citations

Natural Sciences, Chemistry, Catalysis +6