Concepedia

A Three-Dimensional Manganese(II) Complex Exhibiting Ferrimagnetic and Metamagnetic Behaviors

Ruihu Wang, En‐Qing Gao, Maochun Hong, Song Gao, Junhua Luo, Zhenzhong Lin, Lei Han, Rong Cao

Inorganic Chemistry · 2003 · 88 citations · 18 references

DOI

Concepts

Abstract

A three-dimensional complex, [Mn(3)(4-aba)(6)](n) (1) (4-Haba = 4-aminobenzoic acid), consisting of manganese(II) chains and 4-aba bridging ligands, has been synthesized and characterized. Magnetic studies show that the compound behaves as a three-dimensional metamagnet built of homometallic ferrimagnetic chains. The required noncompensation in spin moments is achieved by alternating interactions in an AF-AF-F sequence (AF = antiferromagnetic; F = ferromagnetic) by considering intrachain magnetic interactions.

References

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