Concepedia

A Three-Dimensional Homometallic Molecular Ferrimagnet

Sanjit Konar, Partha Sarathi Mukherjee, Ennio Zangrando, Francesc Lloret, Nirmalendu Ray Chaudhuri

Angewandte Chemie International Edition · 2002 · 204 citations · 9 references

DOI

Concepts

Abstract

Chains of fused NiII octahedral units form a 3D network and thereby the first example of a homometallic 3D ferrimagnet. The material was characterized by X-ray analysis and a low-temperature magnetic study. The structure features an infinite -Ni-(μ3-OH)-Ni2- chain and the spin of adjacent Ni centers alternates between S=1 and S=2 (see picture).

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